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제1장 위험물 기초화학 01 물질의 분류 및 특성 ··································································11 02 원자의 구조 및 주기율표 ···························································19 1. 원자의 구조 ··························································································19 2. 원자와 분자 ··························································································20 3. 화학식량(원자량, 분자량, 몰) ·······························································23 4. 주기율표 ·······························································································27 03 화학식과 화학반응식 ··································································32 1. 화학식 ···································································································32 2. 원자가와 화학 당량 ··············································································37 3. 화학 반응식 ··························································································40 04 기체의 법칙 ················································································45 1. 기체의 압력·온도와 부피의 관계 ··························································45 2. 이상기체 법칙 ·······················································································49 3. 그레이엄의 확산법칙 ············································································51 4. 돌턴(Dalton)의 분압법칙 ·······································································52 05 화학결합 ·····················································································54 1. 이온결합 ·······························································································54 2. 공유결합 ·······························································································55 3. 금속결합 ·······························································································56 4. 기타 화학결합 ·······················································································58 06 산과 염기 ···················································································59 07 용액과 용해도 ············································································65 1. 용액 ······································································································65 2. 용해도 ···································································································67 3. 용액의 농도 ··························································································70 4. 콜로이드 용액 ·······················································································77 08 산화 환원 ·················································································79 1. 산화 환원의 개념 ················································································79 2. 산화수 ···································································································80 3. 산화제와 환원제 ···················································································82 4. 화학전지 ·······························································································83 09 유기화합물 ·················································································89 1. 유기화합물의 분류 ················································································89 2. 알칸 ······································································································94 3. 고리모양 알칸 ·······················································································96 4. 알켄 ······································································································97 5. 알킨 ····································································································100 6. 방향족 화합물 ·····················································································100 연습문제 ·········································································································104 제2장 위험물의 연소 01 연소 이론 ·················································································109 1. 연소의 정의 ························································································109 2. 연소의 구비조건 ·················································································110 3. 온도에 따른 불꽃의 색상 ····································································111 4. 연소의 분류 ························································································112 5. 연소의 형태(물질의 상태에 따른 분류) ···············································113 6. 연소에 관한 물성 ···············································································115 02 발화 ·························································································118 1. 발화의 조건 ························································································118 2. 자연발화 ·····························································································118 3. 혼촉발화 ·····························································································120 03 폭발(explosion) ········································································122 1. 정의 ····································································································122 2. 폭발의 종류 ························································································122 3. 응상폭발 ·····························································································124 4. 폭발의 성립 조건 ···············································································124 5. 폭발의 영향인자 ·················································································125 6. 연소파와 폭굉파 ·················································································128 7. 폭굉 유도거리 ·····················································································128 8. 방폭구조(폭발을 방지하는 구조) ·························································129 9. 정전기 ·································································································130 10. 유류탱크 및 가스탱크에서 발생하는 폭발현상 ·································132 연습문제 ·········································································································134 제3장 위험물의 종류 및 성질 01 제1류 위험물 - 산화성 고체 ······················································144 1. 위험물의 시험방법 ··············································································146 2. 각론 ····································································································149 제1류 위험물 사고사례 ···········································································165 수행 내용1 / 염소산칼륨의 조연성 알아보기 ·········································167 수행 내용2 / 과산화나트륨의 위험성 알아보기 ······································169 수행 내용3 / 제1류 위험물의 위험성평가 ············································171 수행 내용4 / 제1류 위험물 저장 및 취급방법 정보 수집하기 ··············173 수행 결과보고서 ······················································································175 평가자 질문 ·····························································································176 학습자 교수자 공동평가 ········································································177 연습문제 ··································································································178 직무능력평가 ···························································································181 02 제2류 위험물 - 가연성 고체 ·····················································182 1. 위험성 시험방법 ·················································································184 2. 각론 ····································································································186 제2류 위험물 사고사례 ···········································································194 수행 내용1 / 제2류 위험물의 위험성 알아보기 ······································197 수행 내용2 / 유황의 위험성 알아보기 ····················································199 수행 내용3 / 제2류 위험물의 위험성평가 ············································201 수행 내용4 / 제2류 위험물 저장 및 취급방법 정보 수집하기 ··············203 수행 결과보고서 ······················································································205 평가자 질문 ·····························································································206 학습자 교수자 공동평가 ········································································207 연습문제 ··································································································208 직무능력평가 ···························································································211 03 제3류 위험물 - 자연발화성물질 및 금수성물질 ························212 1. 위험물 시험방법 ·················································································213 2. 각론 ····································································································215 제3류 위험물 사고사례 ···········································································226 수행 내용1 / 제3류 위험물의 위험성 알아보기 ······································228 수행 내용2 / 칼슘의 물과의 반응성 알아보기 ········································230 수행 내용3 / 제3류 위험물의 위험성평가 ············································232 수행 내용4 / 제3류 위험물 저장 및 취급방법 정보 수집하기 ··············234 수행 결과보고서 ······················································································236 평가자 질문 ·····························································································237 학습자 교수자 공동평가 ········································································238 연습문제 ··································································································239 직무능력평가 ···························································································242 04 제4류 위험물 - 인화성 액체 ·····················································243 1. 위험물의 시험방법 ··············································································245 2. 각론 ····································································································248 제4류 위험물 사고사례 ···········································································278 수행 내용1 / 제4류 위험물의 물리 화학적 성질 알아보기 ···················280 수행 내용2 / 제4류 위험물의 성상 및 유해성 정보 수집하기 ················282 수행 내용3 / 제4류 위험물의 위험성평가 ············································286 수행 내용4 / 제4류 위험물 저장 및 취급방법 정보 수집하기 ··············288 수행 결과보고서 ······················································································290 평가자 질문 ·····························································································291 학습자 교수자 공동평가 ········································································293 연습문제 ··································································································294 직무능력평가 ···························································································299 05 제5류 위험물 - 자기반응성 물질 ··············································300 1. 위험물의 시험방법 ··············································································302 2. 각론 ····································································································304 제5류 위험물 사고사례 ···········································································316 수행 내용1 / 제5류 위험물 위험성실험 ··················································318 수행 내용2 / 제5류 위험물의 위험성평가 ············································320 수행 내용3 / 제5류 위험물 저장 및 취급방법 정보 수집하기 ··············322 수행 결과보고서 ······················································································324 평가자 질문 ·····························································································325 학습자 교수자 공동평가 ········································································327 연습문제 ··································································································328 직무능력평가 ···························································································331 06 제6류 위험물 - 산화성 액체 ·····················································332 1. 위험물의 시험방법 ··············································································333 2. 각론 ····································································································335 제6류 위험물 사고사례 ···········································································339 수행 내용1 / 과산화수소의 조연성 실험 ················································342 수행 내용2 / 제6류 위험물의 위험성평가 ············································344 수행 내용3 / 제6류 위험물 저장 및 취급방법 정보 수집하기 ··············346 수행 결과보고서 ······················································································348 평가자 질문 ·····························································································349 학습자 교수자 공동평가 ········································································350 연습문제 ··································································································351 직무능력평가 ···························································································352 제4장 위험물 안전 01 위험물의 저장 취급기준 ·························································355 1. 공통기준 ·····························································································355 2. 저장의 기준 ························································································356 3. 취급의 기준 ························································································364 02 위험물 운반기준 ·······································································368 03 위험물의 분류 및 표지에 관한 기준 ········································373 수행 내용1 / 제1류+제2류 혼촉 실험 ····················································381 수행 내용2 / 제1류+제4류 혼촉발화 실험 ·············································383 수행 내용3 / 제4류 위험물 안전카드 작성하기 ······································385 수행 결과보고서 ······················································································388 평가자 질문 ·····························································································389 연습문제 ·········································································································391 부록 국가직무능력표준개발 표준및 활용패키지 ···············································399 위험물의 지정수량 및 주의사항 ······························································424 중요 화학반응식 ······················································································426 해답 ·········································································································427 찾아보기 ··································································································435